W-doped Hierarchically Porous Silica Nanosphere Supported Platinum for Catalytic Glycerol Hydrogenolysis to 1,3-Propanediol
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چکیده
منابع مشابه
Aqueous-Phase Hydrogenolysis of Glycerol over Re Promoted Ru Catalysts Encapuslated in Porous Silica Nanoparticles
Activity improvement of Ru-based catalysts is needed for efficient production of valuable chemicals from glycerol hydrogenolysis. In this work, a series of Re promoted Ru catalysts encapuslated in porous silica nanoparticles (denoted as Re-Ru@SiO₂) were prepared by coating silica onto the surface of chemically reduced Ru-polyvinylpyrrolidone colloids, and were used to catalyze the conversion of...
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A series of ZrO2 supported Ru-Co bimetallic catalysts were prepared and evaluated for the hydrogenolysis of glycerol. The Ru-Co/ZrO2 bimetallic catalyst combines the advantages of both Ru and Co, exhibiting high activity and good selectivity to 1,2-propanediol. The X-ray diffraction (XRD) and TEM results show that higher calcination temperature leads to lower reducibility of cobalt oxides and l...
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Recently, amine-functionalized materials as a prospective chemical sorbent for post combustion CO₂ capture have gained great interest. However, the amine grafting for the traditional MCM-41, SBA-15, pore-expanded MCM-41 or SBA-15 supports can cause the pore volume and specific surface area of sorbents to decrease, significantly affecting the CO₂ adsorption-desorption dynamics. To overcome this ...
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متن کاملGlycerol Valorization: Dehydration to Acrolein Over Silica-Supported Niobia Catalysts
The catalytic dehydration of glycerol to acrolein is investigated over silica-supported niobia catalysts in a continuous fixed-bed gas-phase reactor. Various supported niobia catalysts are prepared and characterized using surface analysis and spectroscopic methods (XRD, UV–Vis, XPS, N2 adsorption), as well as with ammonia adsorption microcalorimetry. Good results are obtained with initial glyce...
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ژورنال
عنوان ژورنال: Acta Chimica Sinica
سال: 2022
ISSN: ['0567-7351']
DOI: https://doi.org/10.6023/a22020059